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Monday 4 June 2012
some scientists and their inventions
here are two awesome scientists and their inventions... John Dalton FRS (6 September 1766 – 27 July 1844) was an English chemist, meteorologist and physicist. He is best known for his pioneering work in the development of modern atomic theory, and his research into colour blindness (sometimes referred to as Daltonism, in his honour). Atomic theory
In 1800, Dalton became a secretary of the Manchester Literary and Philosophical Society, and in the following year he orally presented an important series of papers, entitled "Experimental Essays" on the constitution of mixed gases; on the pressure of steam and other vapours at different temperatures, both in a vacuum and in air; on evaporation; and on the thermal expansion of gases. These four essays were published in the Memoirs of the Lit & Phil in 1802.
The second of these essays opens with the striking remark,
There can scarcely be a doubt entertained respecting the reducibility of all elastic fluids of whatever kind, into liquids; and we ought not to despair of effecting it in low temperatures and by strong pressures exerted upon the unmixed gases further.
After describing experiments to ascertain the pressure of steam at various points between 0 and 100 °C (32 and 212 °F), Dalton concluded from observations on the vapour pressure of six different liquids, that the variation of vapour pressure for all liquids is equivalent, for the same variation of temperature, reckoning from vapour of any given pressure.
In the fourth essay he remarks,
I see no sufficient reason why we may not conclude that all elastic fluids under the same pressure expand equally by heat and that for any given expansion of mercury, the corresponding expansion of air is proportionally something less, the higher the temperature. It seems, therefore, that general laws respecting the absolute quantity and the nature of heat are more likely to be derived from elastic fluids than from other substances.
Atomic weights
Dalton proceeded to print his first published table of relative atomic weights. Six elements appear in this table, namely hydrogen, oxygen, nitrogen, carbon, sulfur, and phosphorus, with the atom of hydrogen conventionally assumed to weigh 1. Dalton provided no indication in this first paper how he had arrived at these numbers.[citation needed] However, in his laboratory notebook under the date 6 September 1803[6] there appears a list in which he sets out the relative weights of the atoms of a number of elements, derived from analysis of water, ammonia, carbon dioxide, etc. by chemists of the time.
It appears, then, that confronted with the problem of calculating the relative diameter of the atoms of which, he was convinced, all gases were made, he used the results of chemical analysis. Assisted by the assumption that combination always takes place in the simplest possible way, he thus arrived at the idea that chemical combination takes place between particles of different weights, and it was this which differentiated his theory from the historic speculations of the Greeks, such as Democritus and Lucretius.[citation needed]
The extension of this idea to substances in general necessarily led him to the law of multiple proportions, and the comparison with experiment brilliantly confirmed his deduction.[7] It may be noted that in a paper on the proportion of the gases or elastic fluids constituting the atmosphere, read by him in November 1802, the law of multiple proportions appears to be anticipated in the words: "The elements of oxygen may combine with a certain portion of nitrous gas or with twice that portion, but with no intermediate quantity", but there is reason to suspect that this sentence may have been added some time after the reading of the paper, which was not published until 1805.
Compounds were listed as binary, ternary, quaternary, etc. (molecules composed of two, three, four, etc. atoms) in the New System of Chemical Philosophy depending on the number of atoms a compound had in its simplest, empirical form.
He hypothesized the structure of compounds can be represented in whole number ratios. So, one atom of element X combining with one atom of element Y is a binary compound. Furthermore, one atom of element X combining with two elements of Y or vice versa, is a ternary compound. Many of the first compounds listed in the New System of Chemical Philosophy correspond to modern views, although many others do not.
Various atoms and molecules as depicted in John Dalton's A New System of Chemical Philosophy (1808).
Dalton used his own symbols to visually represent the atomic structure of compounds. These have made it in New System of Chemical Philosophy where Dalton listed a number of elements, and common compounds.
Five main points of Dalton's atomic theory
Elements are made of extremely small particles called atoms.
Atoms of a given element are identical in size, mass, and other properties; atoms of different elements differ in size, mass, and other properties.
Atoms cannot be subdivided, created, or destroyed.
Atoms of different elements combine in simple whole-number ratios to form chemical compounds.
In chemical reactions, atoms are combined, separated, or rearranged.
Dalton proposed an additional "rule of greatest simplicity" that created controversy, since it could not be independently confirmed.
When atoms combine in only one ratio, "..it must be presumed to be a binary one, unless some cause appear to the contrary".
This was merely an assumption, derived from faith in the simplicity of nature. No evidence was then available to scientists to deduce how many atoms of each element combine to form compound molecules. But this or some other such rule was absolutely necessary to any incipient theory, since one needed an assumed molecular formula in order to calculate relative atomic weights. In any case, Dalton's "rule of greatest simplicity" caused him to assume that the formula for water was OH and ammonia was NH, quite different from our modern understanding.
Despite the uncertainty at the heart of Dalton's atomic theory, the principles of the theory survived. To be sure, the conviction that atoms cannot be subdivided, created, or destroyed into smaller particles when they are combined, separated, or rearranged in chemical reactions is inconsistent with the existence of nuclear fusion and nuclear fission, but such processes are nuclear reactions and not chemical reactions. In addition, the idea that all atoms of a given element are identical in their physical and chemical properties is not precisely true, as we now know that different isotopes of an element have slightly varying weights. However, Dalton had created a theory of immense power and importance. Indeed, Dalton's innovation was fully as important for the future of the science as Antoine Laurent Lavoisier's oxygen-based chemistry had been.
Death and legacy
Bust of Dalton by Chantrey
Painting portrait of Dalton in later life
Dalton suffered a minor stroke in 1837, and a second one in 1838 left him with a speech impediment, though he remained able to do experiments. In May 1844 he had yet another stroke; on 26 July he recorded with trembling hand his last meteorological observation. On 27 July, in Manchester, Dalton fell from his bed and was found lifeless by his attendant. Approximately 40,000 people filed by his coffin as it was laid in state in the Manchester Town Hall.[9] He was buried in Manchester in Ardwick cemetery. The cemetery is now a playing field, but pictures of the original grave are in published materials.[10][11]
A bust of Dalton, by Chantrey, was publicly subscribed for[12] and placed in the entrance hall of the Royal Manchester Institution. Chantrey also crafted a large statue of Dalton, now in the Manchester Town Hall. The statue was erected while Dalton was still alive and it has been said: "He is probably the only scientist who got a statue in his lifetime".[9]
In honour of Dalton's work, many chemists and biochemists use the (as yet unofficial) unit dalton (abbreviated Da) to denote one atomic mass unit, or 1/12 the weight of a neutral atom of carbon-12. There is a John Dalton Street connecting Deansgate and Albert Square in the centre of Manchester.
Manchester Metropolitan University has a building named after John Dalton and occupied by the Faculty of Science and Engineering, in which the majority of its Science & Engineering lectures and classes take place. A statue is outside the John Dalton Building of the Manchester Metropolitan University in Chester Street which has been moved from Piccadilly. It was the work of William Theed (after Chantrey) and is dated 1855 (it was in Piccadilly until 1966).
The University of Manchester has a hall of residence called Dalton Hall; it also established two Dalton Chemical Scholarships, two Dalton Mathematical Scholarships, and a Dalton Prize for Natural History. There is a Dalton Medal awarded occasionally by the Manchester Literary and Philosophical Society (only 12 times altogether).
Dalton Township in southern Ontario was named for Dalton. It has, since 2001, been absorbed into the City of Kawartha Lakes. However the township name was used in a massive new park: Dalton Digby Wildlands Provincial Park, itself renamed since 2002.
A lunar crater has been named after Dalton. "Daltonism" became a common term for colour blindness and "Daltonien" is the actual French word for "colour blind".
The inorganic section of the UK's Royal Society of Chemistry is named after Dalton (Dalton Division), and the Society's academic journal for inorganic chemistry also bears his name (Dalton Transactions).
The name Dalton can often be heard in the halls of many Quaker schools, for example, one of the school houses in Coram House, the primary sector of Ackworth School, is called Dalton.
Much of his collected work was damaged during the bombing of the Manchester Literary and Philosophical Society on 24 December 1940. This event prompted Isaac Asimov to say, "John Dalton's records, carefully preserved for a century, were destroyed during the World War II bombing of Manchester. It is not only the living who are killed in war". The damaged papers are now in the John Rylands Library having been deposited in the university library by the Society.
sir democritus: Democritus (Greek: Δημόκριτος, Dēmokritos, "chosen of the people") (ca. 460 BC – ca. 370 BC) was an Ancient Greek philosopher born in Abdera, Thrace, Greece.[1] He was an influential pre-Socratic philosopher and pupil of Leucippus, who formulated an atomic theory for the cosmos.[2]
His exact contributions are difficult to disentangle from his mentor Leucippus, as they are often mentioned together in texts. Their speculation on atoms, taken from Leucippus, bears a passing and partial resemblance to the nineteenth-century understanding of atomic structure that has led some to regard Democritus as more of a scientist than other Greek philosophers; however their ideas rested on very different bases.[3] Largely ignored in ancient Athens, Democritus was nevertheless well known to his fellow northern-born philosopher Aristotle. Plato is said to have disliked him so much that he wished all his books burned.[1] Many consider Democritus to be the "father of modern science".[4]
Philosophy and science
Democritus followed in the tradition of Leucippus, who seems to have come from Miletus, and he carried on the scientific rationalist philosophy associated with that city. They were both strict determinists and thorough materialists, believing everything to be the result of natural laws. Unlike Aristotle or Plato, the atomists attempted to explain the world without reasoning to purpose, prime mover, or final cause. For the atomists questions should be answered with a mechanistic explanation ("What earlier circumstances caused this event?"), while their opponents search for explanations which, in addition to the material and mechanistic, also included the formal and teleological ("What purpose did this event serve?"). Modern science has focused on mechanistic questions, which have led to scientific knowledge, especially in physics, while teleological questions can be useful in biology, in adaptationist reasoning at providing proximate explanations, though the deeper evolutionary explanations are often held to be thoroughly mechanistic. The atomists looked exclusively for mechanistic questions, and only admitted mechanistic answers. Their successors until the Renaissance became occupied with the teleological question, which arguably hindered progress.[25]
Democritus meditating on the seat of the soul by Léon-Alexandre Delhomme, 1868
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Atomic hypothesis
The theory of Democritus and Leucippus held that everything is composed of "atoms", which are physically, but not geometrically, indivisible; that between atoms lies empty space; that atoms are indestructible; have always been, and always will be, in motion; that there are an infinite number of atoms, and kinds of atoms, which differ in shape, and size. Of the mass of atoms, Democritus said "The more any indivisible exceeds, the heavier it is." But his exact position on weight of atoms is disputed.[1]
Leucippus is widely credited with being the first to develop the theory of atomism, although Isaac Newton preferred to credit the obscure Moschus the Phoenician (whom he believed to be the biblical Moses) as the inventor of the idea on the authority of Posidonius and Strabo.[26] The Stanford Encyclopedia of Philosophy notes, "This theologically motivated view does not seem to claim much historical evidence, however."[27]
Democritus, along with Leucippus and Epicurus, proposed the earliest views on the shapes and connectivity of atoms. They reasoned that the solidness of the material corresponded to the shape of the atoms involved. Thus, iron atoms are solid and strong with hooks that lock them into a solid; water atoms are smooth and slippery; salt atoms, because of their taste, are sharp and pointed; and air atoms are light and whirling, pervading all other materials.[28] Democritus was the main proponent of this view. Using analogies from our sense experiences, he gave a picture or an image of an atom that distinguished them from each other by their shape, their size, and the arrangement of their parts. Moreover, connections were explained by material links in which single atoms were supplied with attachments: some with hooks and eyes others with balls and sockets.[29] The Democritean atom is an inert solid (merely excluding other bodies from its volume) that interacts with other atoms mechanically. In contrast, modern, quantum-mechanical atoms interact via electric and magnetic force fields and are far from inert.
The theory of the atomists appears to be more nearly aligned with that of modern science than any other theory of antiquity. However, the similarity with modern concepts of science can be confusing when trying to understand where the hypothesis came from. It is obvious that classical atomists would never have had a solid empirical basis for our modern concepts of atoms and molecules. Bertrand Russell states that they just hit on a lucky hypothesis, only recently confirmed by evidence.[30] However Lucretius, describing atomism in his De rerum natura gives very clear and compelling empirical arguments for the original atomist theory. He observes that any material is subject to irreversible decay. Through time, even hard rocks are slowly worn down by drops of water. Things have the tendency to get mixed up: mix water with soil and you get mud, that will usually not un-mix by itself. Wood decays. However, we see in nature and technology that there are mechanisms to recreate 'pure' materials like water, air, metals.[citation needed] The seed of an oak will grow out into an oak tree, made of similar wood as historical oak trees, the wood of which has already decayed. The conclusion is that many properties of materials must derive from something inside, that will itself never decay, something that stores for eternity the same inherent, indivisible properties. The basic question is: why has everything in the world not yet decayed, and how can exactly the same materials, plants, animals be recreated again and again? One obvious solution to explain how indivisible properties can be conveyed in a way not easily visible to human senses, is to hypothesise the existence of 'atoms'. These classical 'atoms' are nearer to our modern concept of 'molecule' than to the atoms of modern science.[citation needed] The other big point of classical atomism is that there must be a lot of open space between these 'atoms': the void. Lucretius gives reasonable arguments[citation needed] that the void is absolutely necessary to explain how gasses and fluids can change shape, flow, while metals can be molded, without changing the basic material properties
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Void hypothesis
The atomistic void hypothesis was a response to the paradoxes of Parmenides and Zeno, the founders of metaphysical logic, who put forth difficult to answer arguments in favor of the idea that there can be no movement. They held that any movement would require a void—which is nothing—but a nothing cannot exist. The Parmenidean position was "You say there 'is' a void; therefore the void is not nothing; therefore there is not the void." The position of Parmenides appeared validated by the observation that where there seems to be nothing there is air, and indeed even where there is not matter there is something, for instance light waves.
The atomists agreed that motion required a void, but simply ignored the argument of Parmenides on the grounds that motion was an observable fact. Therefore, they asserted, there must be a void. This idea survived in a refined version as Newton's theory of absolute space, which met the logical requirements of attributing reality to not-being. Einstein's theory of relativity provided a new answer to Parmenides and Zeno, with the insight that space by itself is relative and cannot be separated from time as part of a generally curved space-time manifold. Consequently, Newton's refinement is now considered superfluous.[31]
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Epistemology
The knowledge of truth according to Democritus is difficult, since the perception through the senses is subjective. As from the same senses derive different impressions for each individual, then through the sense-impressions we cannot judge the truth. We can only interpret the sense data through the intellect and grasp the truth, because the truth (aletheia) is at the bottom (en bythoe).
“And again, many of the other animals receive impressions contrary to ours; and even to the senses of each individual, things do not always seem the same. Which then, of these impressions are true and which are false is not obvious; for the one set is no more true than the other, but both are alike. And this is why Democritus, at any rate, says that either there is no truth or to us at least it is not evident.”[32]
“Democritus says: By convention hot, by convention cold, but in reality atoms and void, and also in reality we know nothing, since the truth is at bottom.”[33]
There are two kinds of knowing, the one he calls “legitimate” (gnesie: genuine) and the other “bastard” (skotie: obscure). The “bastard” knowledge is concerned with the perception through the senses, therefore it is insufficient and subjective. The reason is that the sense-perception is due to the effluences of the atoms (aporroai) from the objects to the senses. When these different shapes of atoms come to us, they stimulate our senses according to their shape, and our sense-impressions arise from those stimulations.[34]
The second sort of knowledge, the “legitimate” one, can be achieved through the intellect, in other words, all the sense-data from the “bastard” must be elaborated through reasoning. In this way one can get away from the false perception of the “bastard” knowledge and grasp the truth through the inductive reasoning. After taking into account the sense-impressions, one can examine the causes of the appearances, draw conclusions about the laws that govern the appearances, and discover the causality (aetiologia) by which they are related. This is the procedure of thought from the parts to the whole or else from the apparent to non-apparent (inductive reasoning). This is one example of why Democritus is considered to be an early scientific thinker. The process is reminiscent of that by which science gathers its conclusions.
“But in the Canons Democritus says there are two kinds of knowing, one through the senses and the other through the intellect. Of these he calls the one through the intellect ‘legitimate’ attesting its trustworthiness for the judgement of truth, and through the senses he names ‘bastard’ denying its inerrancy in the discrimination of what is true. To quote his actual words: Of knowledge there are two forms, one legitimate, one bastard. To the bastard belong all this group: sight, hearing, smell, taste, touch. The other is legitimate and separate from that. Then, preferring the legitimate to the bastard, he continues: When the bastard can no longer see any smaller, or hear, or smell, or taste, or perceive by touch, but finer matters have to be examined, then comes the legitimate, since it has a finer organ of perception.”[35]
“In the Confirmations ... he says: But we in actuality grasp nothing for certain, but what shifts in accordance with the condition of the body and of the things (atoms) which enter it and press upon it.”[36]
“Democritus used to say that 'he prefers to discover a causality rather than become a king of Persia'.”[37]
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Ethics and politics
Crying Heraclitus and laughing Democritus, from a 1477 Italian fresco, Pinacoteca di Brera, Milan.
The ethics and politics of Democritus come to us mostly in the form of maxims. He says that "Equality is everywhere noble," but he is not encompassing enough to include women or slaves in this sentiment. Poverty in a democracy is better than prosperity under tyrants, for the same reason one is to prefer liberty over slavery. Those in power should "take it upon themselves to lend to the poor and to aid them and to favor them, then is there pity and no isolation but companionship and mutual defense and concord among the citizens and other good things too many to catalogue." Money when used with sense leads to generosity and charity, while money used in folly leads to a common expense for the whole society— excessive hoarding of money for one's children is avarice. While making money is not useless, he says, doing so as a result of wrong-doing is the "worst of all things." He is on the whole ambivalent towards wealth, and values it much less than self-sufficiency. He disliked violence but was not a pacifist: he urged cities to be prepared for war, and believed that a society had the right to execute a criminal or enemy so long as this did not violate some law, treaty, or oath.[2][31]
Goodness, he believed, came more from practice and discipline than from innate human nature. He believed that one should distance oneself from the wicked, stating that such association increases disposition to vice. Anger, while difficult to control, must be mastered in order for one to be rational. Those who take pleasure from the disasters of their neighbors fail to understand that their fortunes are tied to the society in which they live, and they rob themselves of any joy of their own. He advocated a life of contentment with as little grief as possible, which he said could not be achieved through either idleness or preoccupation with worldly pleasures. Contentment would be gained, he said, through moderation and a measured life; to be content one must set their judgment on the possible and be satisfied with what one has—giving little thought to envy or admiration. Democritus approved of extravagance on occasion, as he held that feasts and celebrations were necessary for joy and relaxation. He considers education to be the noblest of pursuits, but cautioned that learning without sense leads to error.[2][31]
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Mathematics
A right circular cone and an oblique circular cone
Democritus was also a pioneer of mathematics and geometry in particular. We only know this through citations of his works (titled On Numbers, On Geometrics, On Tangencies, On Mapping, and On Irrationals) in other writings, since most of Democritus' body of work did not survive the Middle Ages. Democritus was among the first to observe that a cone or pyramid has one-third the volume of a cylinder or prism respectively with the same base and height. Also, a cone divided in a plane parallel to its base produces two surfaces. He pointed out that if the two surfaces are commensurate with each other, then the shape of the body would appear to be a cylinder, as it is composed of equal rather than unequal circles. However, if the surfaces are not commensurate, then the side of a cone is not smooth but jagged like a series of steps.[38]
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Anthropology, biology, and cosmology
His work on nature is known through citations of his books on the subjects, On the Nature of Man, On Flesh (two books), On Mind, On the Senses, On Flavors, On Colors, Causes concerned with Seeds and Plants and Fruits, and Causes concerned with Animals (three books).[2] He spent much of his life experimenting with and examining plants and minerals, and wrote at length on many scientific topics.[39] Democritus thought that the first humans lived an anarchic and animal sort of life, going out to forage individually and living off the most palatable herbs and the fruit which grew wild on the trees. They were driven together into societies for fear of wild animals, he said. He believed that these early people had no language, but that they gradually began to articulate their expressions, establishing symbols for every sort of object, and in this manner came to understand each other. He says that the earliest men lived laboriously, having none of the utilities of life; clothing, houses, fire, domestication, and farming were unknown to them. Democritus presents the early period of mankind as one of learning by trial and error, and says that each step slowly led to more discoveries; they took refuge in the caves in winter, stored fruits that could be preserved, and through reason and keenness of mind came to build upon each new idea.[2][40]
Democritus held that the Earth was round, and stated that originally the universe was composed of nothing but tiny atoms churning in chaos, until they collided together to form larger units—including the earth and everything on it.[2] He surmised that there are many worlds, some growing, some decaying; some with no sun or moon, some with several. He held that every world has a beginning and an end, and that a world could be destroyed by collision with another world. To epitomize Democritus's cosmology, Russell calls on Shelley: "Worlds on worlds are rolling ever / From creation to decay, / Like the bubbles on a river / Sparkling, bursting, borne away
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